SELENOLANES, SELENATRANS AND ESTERS OF SELENIC ACID
نویسندگان
چکیده
It is known that selenic acid and selenium dioxide act as oxidizing agents in reactions with α-oxides when heated. The proposed paper presents data on the synthesis of organoselenium compounds based its anhydride, where latter selenation agents. was found presence catalytic amounts boron trifluoride esterate oxiranes oxirane ring opens both according to rule against Krasussky formation a mixture α- β- isomers esters. In contrast acid, selendioxide involve expansion form functionally substituted selenolanes. This followed by analysis literature material atranes, unique class heterocyclic distinct biologically active properties, their element derivatives (B, Ge, Si, etc.). For first time we have synthesized selenatranol, which not described literature. future it may only possess bioactive properties itself, like majority compounds, but also be drug precursor. Acetylselenatranol reaction selenatranol acetic anhydride medium. IR, PMR spectra elemental well thermogravimetric (TGA) differential thermal (DTA) some them are given
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ژورنال
عنوان ژورنال: Azerbaj?an himiâ žurnaly
سال: 2022
ISSN: ['2522-1841', '0005-2531']
DOI: https://doi.org/10.32737/0005-2531-2022-4-95-101